CobaltMaghrebV1, France, Analysis, bibRecord, 000335

Structural characterization of a series of cyclohexaphosphates : M0.5((C6H5CH2)2NH2)5P6O18-H2O (M = Co, Cu, Cd)

Identifieur interne : 000335 ( France/Analysis ); précédent : 000334; suivant : 000336

Structural characterization of a series of cyclohexaphosphates : M0.5((C6H5CH2)2NH2)5P6O18-H2O (M = Co, Cu, Cd)

Auteurs : S. Abid [Tunisie] ; M. Rzaigui [Tunisie] ; M. Bagieu-Beucher [France]

Source :

Journal of chemical crystallography [ 1074-1542 ] ; 1999.

RBID : Pascal:00-0210809

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Préparation chimique, Diffraction RX, Structure cristalline, Structure moléculaire, Phosphate cyclique, Cation organique, Cuivre composé, Cadmium composé, Cobalt composé, Spectre IR, Analyse thermique, 6166F, Cyclohexaphosphate, Ammonium(dibenzyl).

English descriptors

KwdEn :
- Cadmium compounds, Chemical preparation, Cobalt compounds, Copper compounds, Crystal structure, Cyclophosphate, Experimental study, Infrared spectra, Molecular structure, Organic cation, Thermal analysis, XRD.

Abstract

Three new cyclohexaphosphates with general formula M_0.5((C₆H₅CH₂)₂NH₂)₅P₆O₁₈-H₂O (M=Co, Cu, Cd) are reported. They crystallize with monoclinic unit-cells and are isotropic. We have determined their structure from the salt M = Co. This later exhibits the following unit-cell parameters: a = 22.739(5), b = 17.682(3), c = 18.342(3) Å, β = 91.22(1)°, Z = 4 P2₁/n, V = 7373 Å³, and Dx = 1.373 g cm^-3. The atomic arrangement can be described as layers containing P₆O₁₈ ring anions and CoO₆ octahedra spreading in the (101) planes and intercalated by the dibenzylammonium groups and the water molecules. Synthesis and charac terization by X-ray diffraction, IR absorption, and TA are described.

Affiliations:

Links toward previous steps (curation, corpus...)

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to stream PascalFrancis, to step Checkpoint: 000294
to stream Main, to step Merge: 000E42
to stream Main, to step Curation: 000E13
to stream Main, to step Exploration: 000E13
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Pascal:00-0210809

Le document en format XML

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((C<sub>6</sub>
H<sub>5</sub>
CH<sub>2</sub>
)<sub>2</sub>
NH<sub>2</sub>
)<sub>5</sub>
P<sub>6</sub>
O<sub>18</sub>
-H<sub>2</sub>
O (M = Co, Cu, Cd)</title>
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((C<sub>6</sub>
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CH<sub>2</sub>
)<sub>2</sub>
NH<sub>2</sub>
)<sub>5</sub>
P<sub>6</sub>
O<sub>18</sub>
-H<sub>2</sub>
O (M = Co, Cu, Cd)</title>
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<author><name sortKey="Bagieu Beucher, M" sort="Bagieu Beucher, M" uniqKey="Bagieu Beucher M" first="M." last="Bagieu-Beucher">M. Bagieu-Beucher</name>
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<term>Chemical preparation</term>
<term>Cobalt compounds</term>
<term>Copper compounds</term>
<term>Crystal structure</term>
<term>Cyclophosphate</term>
<term>Experimental study</term>
<term>Infrared spectra</term>
<term>Molecular structure</term>
<term>Organic cation</term>
<term>Thermal analysis</term>
<term>XRD</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Préparation chimique</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Structure moléculaire</term>
<term>Phosphate cyclique</term>
<term>Cation organique</term>
<term>Cuivre composé</term>
<term>Cadmium composé</term>
<term>Cobalt composé</term>
<term>Spectre IR</term>
<term>Analyse thermique</term>
<term>6166F</term>
<term>Cyclohexaphosphate</term>
<term>Ammonium(dibenzyl)</term>
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<front><div type="abstract" xml:lang="en">Three new cyclohexaphosphates with general formula M<sub>0.5</sub>
((C<sub>6</sub>
H<sub>5</sub>
CH<sub>2</sub>
)<sub>2</sub>
NH<sub>2</sub>
)<sub>5</sub>
P<sub>6</sub>
O<sub>18</sub>
-H<sub>2</sub>
O (M=Co, Cu, Cd) are reported. They crystallize with monoclinic unit-cells and are isotropic. We have determined their structure from the salt M = Co. This later exhibits the following unit-cell parameters: a = 22.739(5), b = 17.682(3), c = 18.342(3) Å, β = 91.22(1)°, Z = 4 P2<sub>1</sub>
/n, V = 7373 Å<sup>3</sup>
, and Dx = 1.373 g cm<sup>-3</sup>
. The atomic arrangement can be described as layers containing P<sub>6</sub>
O<sub>18</sub>
 ring anions and CoO<sub>6</sub>
 octahedra spreading in the (101) planes and intercalated by the dibenzylammonium groups and the water molecules. Synthesis and charac terization by X-ray diffraction, IR absorption, and TA are described.</div>
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Structural characterization of a series of cyclohexaphosphates : M0.5((C6H5CH2)2NH2)5P6O18-H2O (M = Co, Cu, Cd)

Structural characterization of a series of cyclohexaphosphates : M0.5((C6H5CH2)2NH2)5P6O18-H2O (M = Co, Cu, Cd)

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri